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1

Kinetics and mechanisms of elimination of ethyl 3-phenyl and ethyl 3-methyl-3-phenyl glycidates in the gas phase

Gabriel Chuchani, María Tosta, Alexandra Rotinov, Armando Herize

Journal:

Journal of Physical Organic Chemistry

Year:

2004

Language:

english

File:

PDF, 103 KB

english, 2004

2

The gas-phase pyrolysis of several aliphatic 1,3-diols. The kinetic and mechanism of 2,4-dimethyl-2,4-pentanediol

Gabriel Chuchani, Rosa M. Dominguez, Alexandra Rotinov, Ignacio Martin

Journal:

International Journal of Chemical Kinetics

Year:

1997

Language:

english

File:

PDF, 124 KB

english, 1997

3

The kinetics and mechanisms of gas phase elimination of primary, secondary, and tertiary 2-hydroxyalkylbenzenes

Gabriel Chuchani, Alexandra Rotinov, Rosa M. Dominguez

Journal:

International Journal of Chemical Kinetics

Year:

1999

Language:

english

File:

PDF, 149 KB

english, 1999

4

Homogeneous, unimolecular, gas-phase elimination of leaving groups at the alkoyl side of carboxylic acids

Gabriel Chuchani, Alexandra Rotinov, Rosa M. Dominguez, Ignacio Martin

Journal:

Journal of Physical Organic Chemistry

Year:

1996

Language:

english

File:

PDF, 460 KB

english, 1996

5

Elimination kinetics and mechanisms for several 2-alkoxyacetic acids in the gas phase

Gabriel Chuchani, Alexandra Rotinov, Rosa M. Dominguez

Journal:

Journal of Physical Organic Chemistry

Year:

1996

Language:

english

File:

PDF, 4.88 MB

english, 1996

6

Elimination kinetics of β-hydroxynitriles in the gas phase

Gabriel Chuchani, Rosa M. Dominguez, Alexandra Rotinov, Jairo Quijano, Cristina Valencia, Bernardo Vicente, Dimas Franco

Journal:

Journal of Physical Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 63 KB

english, 1999

7

Gas-phase elimination kinetics of ethyl, isopropyl and tert-butyl N,N-diethylcarbamates. application of taft–topsom correlation for substituents other than carbon at the acid side of organic ethyl esters

Armando Herize, Rosa M. Dominguez, Alexandra Rotinov, Oswaldo Nuñez, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 63 KB

english, 1999

8

Pyrolysis kinetics of 2-phenoxycarboxylic acids in the gas phase

Gabriel Chuchani, Rosa M. Dominguez, Alexandra Rotinov, Ignacio Martin

Journal:

Journal of Physical Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 67 KB

english, 1999

9

Neighbouring group participation in the gas-phase pyrolysis kinetics of 4-(N-methyl-N-phenylamino)-1-butyl acetate and 4-(N-phenylamino)-1-butyl acetate

Gabriel Chuchani, Nouria Al-Awadi, Rosa M. Domínguez, Alexandra Rotinov, Armando Herize, Kamini Kaul

Journal:

Journal of Physical Organic Chemistry

Year:

2000

Language:

english

File:

PDF, 64 KB

english, 2000

10

Steric factors in the gas phase elimination kinetics of ethyl N-benzyl-N-cyclopropylcarbamate and ethyl diphenylcarbamate

Marniev Luiggi, Rosa M. Dominguez, Alexandra Rotinov, Armando Herize, Mary Cordova, Gabriel Chuchani

Journal:

International Journal of Chemical Kinetics

Year:

2002

Language:

english

File:

PDF, 126 KB

english, 2002

11

The mechanism of neutral amino acid decomposition in the gas phase. The elimination kinetics of N,N-dimethylglycine ethyl ester, ethyl 1-piperidineacetate, and N,N-dimethylglycine

Adolfo Ensuncho, M. Jennifer Lafont, Alexandra Rotinov, Rosa M. Domínguez, Armando Herize, Gabriel Chuchani, Jairo Quijano

Journal:

International Journal of Chemical Kinetics

Year:

2001

Language:

english

File:

PDF, 76 KB

english, 2001

12

The kinetics and mechanisms of the gas-phase unimolecular eliminations of halogeno esters. Participation of the carbomethoxy group

Gabriel Chuchani, Alexandra Rotinov, Rosa M. Dominguez

Journal:

International Journal of Chemical Kinetics

Year:

1982

Language:

english

File:

PDF, 691 KB

english, 1982

13

Linear correlation of polar substituents in the gas-phase pyrolyses of ethyl α-substituted acetates

Alexandra Rotinov, Gabriel Chuchani

Journal:

International Journal of Chemical Kinetics

Year:

1984

Language:

english

File:

PDF, 317 KB

english, 1984

14

The intimate ion pair mechanism in the maximally inhibited elimination kinetics of methyl 4-chlorobutyrate and methyl 5-chlorovalerate in the gas phase

Gabriel Chuchani, Rosa M. Dominguez, Alexandra Rotinov

Journal:

International Journal of Chemical Kinetics

Year:

1986

Language:

english

File:

PDF, 458 KB

english, 1986

15

The mechanisms of the homogeneus, unimolecular elimination kinetics of ethyl 4-chlorobutyrate and 4-chlorobutyric acid in the gas phase

Gabriel Chuchani, Alexandra Rotinov

Journal:

International Journal of Chemical Kinetics

Year:

1987

Language:

english

File:

PDF, 375 KB

english, 1987

16

The maximally inhibited gas phase pyrolysis kinetics of primary alkyl bromides. The taft correlation of alkyl substituents

Gabriel Chuchani, Alexandra Rotinov, Rosa M. Dominguez, Ignacio Martin

Journal:

International Journal of Chemical Kinetics

Year:

1987

Language:

english

File:

PDF, 174 KB

english, 1987

17

The effect of ring size on the gas phase elimination kinetics of cycloalkyl acetates

Gabriel Chuchani, Ignacio Martin, Alexandra Rotinov, Rosa M. Dominguez, David G. Morris, Alistair G. Shepherd

Journal:

International Journal of Chemical Kinetics

Year:

1988

Language:

english

File:

PDF, 346 KB

english, 1988

18

The mechanism in the elimination kinetics of 2-chloropropionic acid in the gas phase

Gabriel Chuchani, Alexandra Rotinov

Journal:

International Journal of Chemical Kinetics

Year:

1989

Language:

english

File:

PDF, 233 KB

english, 1989

19

The elimination kinetics of secondary Alkyl Bromides in the gas phase

Gabriel Chuchani, Ignacio Martín, Alexandra Rotinov, Rosa M. Domínguez

Journal:

International Journal of Chemical Kinetics

Year:

1990

Language:

english

File:

PDF, 349 KB

english, 1990

20

The kinetics and mechanisms of methyl 2-bromopropionate and 2-bromopropionic acid pyrolyses under maximum inhibition

Gabriel Chuchani, Rosa M. Dominguez, Alexandra Rotinov

Journal:

International Journal of Chemical Kinetics

Year:

1991

Language:

english

File:

PDF, 280 KB

english, 1991

21

The retro-aldol mechanism in the pyrolysis kinetics of primary, secondary, and tertiary β-hydroxy ketones in the gas phase

Alexandra Rotinov, Gabriel Chuchani, Ruben A. Machado, Carlos Rivas, Jairo Quijano, Maria Del Socorro Yepes, Iliana Restrepo

Journal:

International Journal of Chemical Kinetics

Year:

1992

Language:

english

File:

PDF, 400 KB

english, 1992

22

The gas-phase elimination kinetics of 2-hydroxy-2-methylbutyric acid and 2-ethyl-2-hydroxybutyric acid

Gabriel Chuchani, Ignacio Martin, Alexandra Rotinov

Journal:

International Journal of Chemical Kinetics

Year:

1995

Language:

english

File:

PDF, 294 KB

english, 1995

23

The kinetics and mechanisms of gas phase elimination of the ethyl ester of amino acid hydrochlorides

Gabriel Chuchani, Armando Herize, Rosa María Domínguez, Alexandra Rotinov, Maria Tosta

Journal:

Journal of Physical Organic Chemistry

Year:

2006

Language:

english

File:

PDF, 104 KB

english, 2006

24

A structure–reactivity correlation with three slopes in the elimination kinetics of 2–substituted ethyl N,N-dimethylcarbamates in the gas phase

Gabriel Chuchani, Oswaldo Nunñez, Norka Marcano, Suvighey Napolitano, Henry Rodriguez, Marianella Domínguez, Judany Ascanio, Alexandra Rotinov, Rosa M. Domínguez, Armando Herize

Journal:

Journal of Physical Organic Chemistry

Year:

2001

Language:

english

File:

PDF, 137 KB

english, 2001

25

Kinetics of elimination of several heterocyclic carbamates in the gas phase

Yannely Brusco, Rosa M. Domínguez, Alexandra Rotinov, Armando Herize, Mary Cordova, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 72 KB

english, 2002

26

Mechanism of elimination of amino acid derivatives in the gas phase. Pyrolysis kinetics of ethyl picolinate, ethyl 1-methylpipecolinate and picolinic acid

Jennifer Lafont, Adolfo Ensuncho, Rosa M. Domínguez, Alexandra Rotinov, Armando Herize, Jairo Quijano, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

2003

Language:

english

File:

PDF, 75 KB

english, 2003

27

Kinetics and mechanisms of the gas-phase elimination of arylethyl N,N-dimethylcarbamates and ω-phenylalkyl N,N-dimethylcarbamates

Gabriel Chuchani, Rosa M. Dominguez, Alexandra Rotinov, Armando Herize

Journal:

Journal of Physical Organic Chemistry

Year:

2003

Language:

english

File:

PDF, 85 KB

english, 2003

28

Molecular rearrangements in homogeneous gas-phase elimination reactions. Pyrolysis kinetics of alkyl methanesulphonates

Gabriel Chuchani, Ignacio Martin, Rosa M. Dominguez, Alexandra Rotinov, Sara Pekerarm, Matilde Gomez

Journal:

Journal of Physical Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 543 KB

english, 1993

29

Elimination kinetics and mechanism of primary, secondary and tertiary α-hydroxycarboxylic acids in the gas phase

Gabriel Chuchani, Ignacio Martin, Alexandra Rotinov, Rosa M. Dominguez

Journal:

Journal of Physical Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 293 KB

english, 1993

30

Participation and rearrangement in the gas-phase elimination kinetics of 3-(o-methoxyphenyl)propyl-1-methanesulphonate and 4-(p-methoxyphenyl)butyl-1-methanesulphonate

Ignacio Martin, Gabriel Chuchani, Rosa Dominguez, Alexandra Rotinov

Journal:

Journal of Physical Organic Chemistry

Year:

1992

Language:

english

File:

PDF, 401 KB

english, 1992

31

Several mechanisms in the elimination kinetics of ω-chlorocarboxylic acids in the gas phase

Gabriel Chuchani, Ignacio Martin, Alexandra Rotinov, Rosa M. Dominguez, Perez I. Milagros

Journal:

Journal of Physical Organic Chemistry

Year:

1995

Language:

english

File:

PDF, 436 KB

english, 1995

32

Experimental and theoretical study of the homogeneous, unimolecular gas-phase elimination kinetics of methyl oxalyl chloride

Tania Cordova, Alexandra Rotinov, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

2004

Language:

english

File:

PDF, 74 KB

english, 2004

33

Kinetics and mechanisms of the gas-phase elimination of 2-substituted primary, secondary and tertiary hydroxy groups in nitroalkanes

Rosa María Domínguez, Armando Herize, Alexandra Rotinov, Alvaro Alvarez-Aular, Gonzalo Visbal, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

2004

Language:

english

File:

PDF, 145 KB

english, 2004

34

Kinetics and mechanisms of the elimination of ethyl and tert-butyl esters of carbazic acid in the gas phase: experimental and theoretical studies

Alexandra Rotinov, Rosa M. Domínguez, Tania Córdova, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

2005

Language:

english

File:

PDF, 388 KB

english, 2005

35

Experimental and theoretical studies of the elimination kinetics of 3-hydroxy-3-methyl-2-butanone in the gas phase

Mariana Graterol, Alexandra Rotinov, Tania Cordova, Gabriel Chuchani

Journal:

Journal of Physical Organic Chemistry

Year:

2005

Language:

english

File:

PDF, 456 KB

english, 2005

36

A combined experimental and theoretical study of the unimolecular elimination kinetics of 2-alkoxypropionic acids in the gas phase

Alexandra Rotinov, Gabriel Chuchani, Juan Andrés, Luis R. Domingo, V.Sixte Safont

Journal:

Chemical Physics

Year:

1999

Language:

english

File:

PDF, 289 KB

english, 1999

37

Analysis of operation of filters for post-accident decontamination of pressurized rooms of a nuclear power plants with a type VVER-440 reactor

L. I. Zaichik, Yu. A. Zeigarnik, A. G. Rotinov, A. S. Sidorov, N. N. Silina, R. F. Chalyi

Journal:

Thermal Engineering

Year:

2007

Language:

english

File:

PDF, 274 KB

english, 2007

38

Use of combined-cycle power units at cogeneration plants

V. M. Batenin, Yu. A. Zeigarnik, V. M. Maslennikov, Yu. L. Shekhter, A. G. Rotinov

Journal:

Thermal Engineering

Year:

2008

Language:

english

File:

PDF, 142 KB

english, 2008

39

Expedient arrangement of newly constructed systems for centralized heat supply

Yu. A. Zeigarnik, A. G. Rotinov

Journal:

Thermal Engineering

Year:

2008

Language:

english

File:

PDF, 83 KB

english, 2008

40

ChemInform Abstract: Homogeneous, Unimolecular, Gas-Phase Elimination of Leaving Groups at the Alkoyl Side of Carboxylic Acids

G. CHUCHANI, A. ROTINOV, R. M. DOMINGUEZ, I. MARTIN

Journal:

Year:

1996

File:

PDF, 26 KB

1996

41

Evidence of polar effects of substituents in the gas phase unimolecular elimination of β-substituted ethyl chlorides. Pyrolysis of 3-chloro-2-methylpropionitrile

G. Chuchani, A. Rotinov

Journal:

Reaction Kinetics, Mechanisms and Catalysis

Year:

1979

Language:

english

File:

PDF, 216 KB

english, 1979

42

Elimination kinetics of tertiary alcohols catalyzed by HBr in the gas phase

Gabriel Chuchani, Rosa M. Domínguez, Alexandra Rotinov, Ignació Martín

Journal:

Reaction Kinetics, Mechanisms and Catalysis

Year:

1991

Language:

english

File:

PDF, 248 KB

english, 1991

43

Gas phase unimolecular elimination of some ortho-substituted β-phenylethyl acetates

G. Chuchani, A. Rotinov, D. F. Caraballo, J. D. Medina

Journal:

Reaction Kinetics, Mechanisms and Catalysis

Year:

1980

Language:

english

File:

PDF, 189 KB

english, 1980

44

Assessment of the methoxy substituent effect in the gas phase elimination of methoxyalkyl acetates

G. Chuchani, A. Rotinov

Journal:

Reaction Kinetics, Mechanisms and Catalysis

Year:

1978

Language:

english

File:

PDF, 221 KB

english, 1978

45

Pyrolysis kinetics of methoxyphenyl chloroalkanes

Gabriel Chuchani, Alexandra Rotinov

Journal:

Reaction Kinetics, Mechanisms and Catalysis

Year:

1989

Language:

english

File:

PDF, 235 KB

english, 1989

46

Kinetics and mechanism of elimination of methoxyphenethyl chlorides in the gas phase

R. M. Domînguez, A. Rotinov, J. A. Hernández, A. I. Martín, J. D. Medina, G. Chuchani

Journal:

Reaction Kinetics, Mechanisms and Catalysis

Year:

1987

Language:

english

File:

PDF, 330 KB

english, 1987

47

Gas Phase Elimination Kinetics of Methyl Mandelate: Experimental and DFT Studies

Rotinov, Alexandra, Escalante, Luz, Ramirez, Beatriz, Pereira, Desiree, Córdova, Tania, Chuchani, Gabriel

Journal:

Journal of Physical Chemistry A

Year:

2009

Language:

english

File:

PDF, 972 KB

english, 2009

48

Joint Experimental and Theoretical Studies of the Mechanism for the Gas Phase Elimination Kinetics of Methyl 2,2-Dimethyl-3-hydroxypropionate

Rotinov, Alexandra, Ramirez, Beatriz, Escalante, Luz, Pereira, Desiree, Córdova, Tania, Chuchani, Gabriel

Journal:

Journal of Physical Chemistry A

Year:

2009

Language:

english

File:

PDF, 302 KB

english, 2009

49

A Combined Experimental and Theoretical Study of the Homogeneous, Unimolecular Decomposition Kinetics of 3-Chloropivalic Acid in the Gas Phase

Chuchani, Gabriel, Rotinov, Alexandra, Andrés, Juan, Domingo, Luís R., Safont, V. Sixte

Journal:

Journal of Physical Chemistry A

Year:

2001

Language:

english

File:

PDF, 148 KB

english, 2001

50

Kinetics and mechanism of elimination of primary alkyl methanesulfonates in the gas phase: correlation of alkyl substituents

Chuchani, Gabriel, Pekerar, Sarah, Dominguez, Rosa M., Rotinov, Alexandra, Martin, Ignacio

Journal:

Journal of Physical Chemistry

Year:

1989

Language:

english

File:

PDF, 261 KB

english, 1989

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